1010 - Relative Rates |
1010 - Express a rate of change as the ratio of a property change over a change in time (rate = Δ X/ Δ t ; Δ X = Xf - Xi). |
1020 - Relate a rate of reaction to a change in extent (usually concentration) of reactants over time. |
1030 - Define rate of reaction as rate of change divided by the coefficient for each participant in a balanced equation. |
1040 - Recognize reactant coefficients are negative when applying the definition for rate of reaction. |
1050 - Use rate of reaction to determine the instantaneous rate of change of any reaction component. |
1070 - Calculate an average rate of reaction and predict a change in concentration from a plot of concentration vs. time. |
1080 - Know absorbance and transmittance can be measured experimentally with spectroscopy. |
1085 - Relate transmittance (T) to absorbance ( A = 2 log(%T) ) |
1090 - Relate concentration (c) to absorbance (A) with Beers law ( A = e L c ) |
1020 - Differential Rate Laws |
1005 - Recognize rate of reaction is determined experimentally and may change with concentraiton. |
1020 - Express rate of reaction generically as rate = k[A]^n (a differential rate law). |
1040 - Recognize reactions are most commonly zero order, first order or second order (others are possible). |
1060 - Determine order of a reaction by inspection of initial rates for different concentrations. |
1070 - Calculate order of reaction by a ratio of rates to the log of a ratio of concentrations. |
1080 - From experimental data, solve for a rate law that has multiple reactants. |
1090 - Classify a reaction by its reaction order (n), overall and by each component. |
1100 - Solve for a rate constant (k) and its units, given a rate law, rate and initial concentrations. |
1030 - Integrated Rate Laws |
1010 - Know the form of zeroeth, first and second order rate laws integrated over time (integrated rate laws). |
1020 - Know which graph of [A], ln[A] or 1/[A] vs time is linear for zeroeth, first and second order reactions. |
1030 - Find k from a graph of [A], ln[A] and 1/[A] vs time for zeroeth, first and second order reactions. |
1040 - Find the half-life equation of a reaction by substituting 1/2 [A]o into a zeroeth, first and second order rate law. |
1050 - Know half-lives are constant for first order reactions, shrink over time for zeroeth order, and grow for second order. |
1060 - Find the half-life or k, given the other for a first order reaction (or given the other and [A]o for a 0th or 2nd order). |
1070 - Relate time, concentration, half-life and initial concentration. Given three solve for the fourth. |