Rate

(Lecture id-1118)

TOPICS & OBJECTIVES

1010 - Relative Rates
    1010 - Express a rate of change as the ratio of a property change over a change in time (rate = Δ X/ Δ t ; Δ X = Xf - Xi).
    1020 - Relate a rate of reaction to a change in extent (usually concentration) of reactants over time.
    1030 - Define rate of reaction as rate of change divided by the coefficient for each participant in a balanced equation.
    1040 - Recognize reactant coefficients are negative when applying the definition for rate of reaction.
    1050 - Use rate of reaction to determine the instantaneous rate of change of any reaction component.
    1070 - Calculate an average rate of reaction and predict a change in concentration from a plot of concentration vs. time.
    1080 - Know absorbance and transmittance can be measured experimentally with spectroscopy.
    1085 - Relate transmittance (T) to absorbance ( A = 2 log(%T) )
    1090 - Relate concentration (c) to absorbance (A) with Beers law ( A = e L c )
 
1020 - Differential Rate Laws
    1005 - Recognize rate of reaction is determined experimentally and may change with concentraiton.
    1020 - Express rate of reaction generically as rate = k[A]^n (a differential rate law).
    1040 - Recognize reactions are most commonly zero order, first order or second order (others are possible).
    1060 - Determine order of a reaction by inspection of initial rates for different concentrations.
    1070 - Calculate order of reaction by a ratio of rates to the log of a ratio of concentrations.
    1080 - From experimental data, solve for a rate law that has multiple reactants.
    1090 - Classify a reaction by its reaction order (n), overall and by each component.
    1100 - Solve for a rate constant (k) and its units, given a rate law, rate and initial concentrations.
 
1030 - Integrated Rate Laws
    1010 - Know the form of zeroeth, first and second order rate laws integrated over time (integrated rate laws).
    1020 - Know which graph of [A], ln[A] or 1/[A] vs time is linear for zeroeth, first and second order reactions.
    1030 - Find k from a graph of [A], ln[A] and 1/[A] vs time for zeroeth, first and second order reactions.
    1040 - Find the half-life equation of a reaction by substituting 1/2 [A]o into a zeroeth, first and second order rate law.
    1050 - Know half-lives are constant for first order reactions, shrink over time for zeroeth order, and grow for second order.
    1060 - Find the half-life or k, given the other for a first order reaction (or given the other and [A]o for a 0th or 2nd order).
    1070 - Relate time, concentration, half-life and initial concentration. Given three solve for the fourth.
 


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